Síntesis y caracterización de dos materiales azo: Comparación  entre un compuesto sulfonado y su análogo no sulfonado

Byron Lopez Mayorga; Edward M. A. Guerrero-Gutiérrez; Allan Vásquez-Bolaños; José Castillo-Arroyave; Heriberto Pfeiffer

doi:10.36829/63CTS.v11i1.1596

Authors

Byron Lopez Mayorga Universidad de San Carlos de Guatemala https://orcid.org/0000-0001-7165-6283
Edward M. A. Guerrero-Gutiérrez Escuela de Ingeniería Química, Facultad de Ingeniería, Universidad de San Carlos de Guatemala https://orcid.org/0000-0002-5778-3953
Allan Vásquez-Bolaños Escuela de Química
José Castillo-Arroyave Escuela de Química, Facultad de Ciencias Químicas y Farmacia, Universidad de San Carlos de Guatemala
Heriberto Pfeiffer https://orcid.org/0000-0002-6623-5780

DOI:

https://doi.org/10.36829/63CTS.v11i1.1596

Keywords:

Sulfonic group, hysteresis, azo compound, thermal degradation

Abstract

This research aimed at the synthesis and characterization of two new azo materials obtained through a clas
sical diazotization reaction. The first material (A1) was synthesized via the reaction between fluoroglucinol
and p-phenylenediamine, while the second material (A2) was obtained from the reaction between fluoroglucinol
and 2,5-diaminobenzenesulfonic acid. These materials were chemically characterized using Fourier-Transform
Infrared Spectroscopy (FTIR-ATR). Additionally, their thermal stability was evaluated through thermogravime
tric analysis (TGA), and their crystalline structure was determined using powder X-ray diffraction (XRD). The
results indicate that A2 exhibits a higher water absorption capacity attributable to sulfonic groups. Furthermore,
both materials initiate degradation above 140 °C and exhibit an amorphous nature with a surface area less than
1 m²g^-1. It is noteworthy that A2 possesses an order of magnitude higher to absorb N₂ than A1. Both materials
showed type III isotherm nitrogen adsorption characteristics, suggesting low interaction energies and properties of non-porous materials.

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